页岩中的石英类型、成因及意义<sup>*</sup>

doi:10.7605/gdlxb.2024.02.038

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Abstract

Quartz is an important part of shale,making it crucial to clarify its genetic mechanism for the reconstruction of shale diagenetic process and the formation of shale oil and gas reservoir. The genesis of quartz in shale is complex,with the main types, including terrigenous detrital quartz,biogenic quartz and diagenetic authigenic quartz, identifiable through ordinary thin section observation,scanning electron microscopy,energy spectrum analysis and cathodoluminescence. The main sources of diagenetic authigenic quartz silica are clay mineral transformation,felsic dissolution and biosilicon dissolution,and volcano-hydrothermal activity. Terrigenous detrital quartz is mostly silt-grade and strongly emits light under cathodoluminescence,typically displaying a two-peak spectrum. Micron-sized biogenic quartz does not emit light,and clay mineral-derived quartz is predoninantly found around or embedded within clay minerals, such as illite. In addition to the morphology and occurrence characteristics of different types of quartz,there are also differences in geochemical elements. Quartz affected by hydrothermal activities is rich in Fe and Mn,while terrigenous detrital quartz is rich in Ti and Al elements. Detrital SiO₂ and Zr are positive correlation,as does biogenic quartz with TOC content. The biogenic quartz Fe/Ti ranges between 0.4 and 20. Diagenetic authigenic quartz is formed in multiple stages,which is closely related to the burial diagenesis process of shale and affects the properties of shale reservoirs. Diagenetic authigenic quartz is mainly formed in early and middle diagenetic stages. Terrigenous detrital quartz and biogenic quartz are conducive to inhibiting compaction and protecting primary pores. Processes involving diagenetic authigenic quartz, like clay mineral transformation and felsic dissolution create dissolution pores and organic pores,with quartz filling some pores,thereby reducing porosity. Identifying the origin of quartz in shale is of great significance to the analysis of shale sedimentary environment and the prediction of favorable reservoir distribution.

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	Articles by authors
	MEI Junfang
	LIANG Chao
	CAO Yingchang
	HAN Yu

Key words： quartz silicon cycle siliceous source genetic mechanism diagenetic evolution shale reservoir

Received: 09 May 2023

ZTFLH:

P571

Fund:

Co-funded by the National Natural Science Foundation of China(Nos. 42172165,41902134),the Fundamental Research Funds for the Central Universities(No.22CX06001A)and the Taishan Scholars Program(No. TSQN201812030)

Corresponding Authors: LIANG Chao,born in 1986,professor,is mainly engaged in fine-grained sedimentology research. E-mail: liangchao0318@163.com.

About author: MEI Junfang,born in 2000,a master degree candidate,is engaged in fine-grained sedimentology research. E-mail: s21010031@s.upc.edu.cn.

Cite this article:

MEI Junfang,LIANG Chao,CAO Yingchang et al. Types,genesis and significance of quartz in shales[J]. JOPC, 2024, 26(2): 487-501.

URL:

http://www.gdlxb.cn/EN/10.7605/gdlxb.2024.02.038 OR http://www.gdlxb.cn/EN/Y2024/V26/I2/487

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